Konstantinos Kavallieratos
- Associate Professor, Chemistry and Biochemistry , College of Arts, Sciences & Education
Publications
selected publications
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Article
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2020Mercury (II) sensing via cyclization of a dithioamide into a benzimidazole derivative: A structural and spectroscopic study. INORGANICA CHIMICA ACTA. 510.Full Text via DOI: 10.1016/j.ica.2020.119680 Web of Science: 000541377100007
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2020Spectroscopic and Theoretical Insights into Surprisingly Effective Sm(III) Extraction from Alkaline Aqueous Media by o-Phenylenediamine-Derived Sulfonamides. INORGANIC CHEMISTRY. 59:6884-6894.Full Text via DOI: 10.1021/acs.inorgchem.0c00309 Web of Science: 000535304900026
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2019Coordination polymers of Cd-II and Pb-II with croconate show remarkable differences in coordination patterns: a structural and spectroscopic study. ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY. 75:935-+.Full Text via DOI: 10.1107/S2053229619007277 Web of Science: 000474222100014
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2019Soft-donor dipicolinamide derivatives for selective actinide(iii)/lanthanide(iii) separation: the role of S- vs. O-donor sites. CHEMICAL COMMUNICATIONS. 55.Full Text via DOI: 10.1039/c8cc07683a Web of Science: 000459474300004
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20181,3,5-Tris-(4-(iso-propyl)-phenylsulfamoylmethyl)benzene as a potential Am(III) extractant: experimental and theoretical study of Sm(III) complexation and extraction and theoretical correlation with Am(III). MOLECULAR PHYSICS. 116.Full Text via DOI: 10.1080/00268976.2018.1471228 Web of Science: 000442634600031
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20181,3,5-Tris-(4-(iso-propyl)-phenylsulfamoylmethyl)benzene as a potential Am(III) extractant: experimental and theoretical study of Sm(III) complexation and extraction and theoretical correlation with Am(III). MOLECULAR PHYSICS. 116.Full Text via DOI: 10.1080/00268976.2018.1471228 Web of Science: 000442634600031
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2017Remarkably selective NH4+ binding and fluorescence sensing by tripodal tris(pyrazolyl) receptors derived from 1,3,5-triethylbenzene: structural and theoretical insights on the role of ion pairing. NEW JOURNAL OF CHEMISTRY. 41:14835-14838.Full Text via DOI: 10.1039/c7nj03213g Web of Science: 000417058800005
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2013Kinetic analysis of DAF-FM activation by NO: Toward calibration of a NO-sensitive fluorescent dye. NITRIC OXIDE-BIOLOGY AND CHEMISTRY. 28:39-46.
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2012Glutathiyl radical as an intermediate in glutathione nitrosation. FREE RADICAL BIOLOGY AND MEDICINE. 53:1968-1976.Full Text via DOI: 10.1016/j.freeradbiomed.2012.08.013 PMID: 22951977 Web of Science: 000311328300016
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2009Speciation, formation, stability and analytical challenges of human arsenic metabolites. JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY. 24:1397-1405.
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2006Investigation of disulfonamide ligands derived from o-phenylenediamine and their Pb(II) complexes by electrospray ionization mass spectrometry. RAPID COMMUNICATIONS IN MASS SPECTROMETRY. 20:303-308.
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2005N,N '-(o-phenylene)dibenzenesulfonamide. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE. 61.Full Text via DOI: 10.1107/S1600536805001133 Web of Science: 000226692400160
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2005Fluorescent sensing and selective Pb(II) extraction by a dansylamide ion-exchanger. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 127:6514-6515.
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2005Identification of anionic supramolecular complexes of sulfonamide receptors with Cl-, NO3-, Br-, and I- by APCI-MS. JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY. 16:1377-1383.
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2005Pb(II) coordination and synergistic ion-exchange extraction by combinations of sulfonamide chelates and 2,2 '-bipyridine. INORGANIC CHEMISTRY. 44:2573-2575.
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2005Structural insights into the coordination and extraction of Pb(II) by disulfonamide ligands derived from o-phenylenediamine. INORGANIC CHEMISTRY. 44:7951-7959.
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Meeting Abstract
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2019Coordination chemistry of the rhodizonate anion with divalent toxic metals: Binary and ternary rhodizonate complexes for spectrophotometric M(II) detection. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.Web of Science: 000478861202198
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2019Mercury (II) complexes derived from N, N- and N, S-donor ligands. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.Web of Science: 000478861202264
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2019Ortho-nitrophenyl photolyzable ligands as cages for tb(III) and other lanthanides. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.Web of Science: 000478861201359
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2019Oxoamide and thioamide ligands for solvent extraction applications from used nuclear fuel: Investigating actinide vs lanthanide extraction selectivity. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.Web of Science: 000478861203144
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2019Sulfonamide and thioamide chelators as mercury extractants and sensors for potential application to high-level waste processing at the savannah river site. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.Web of Science: 000478861202050
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2019Trisulfonamide and o-sulfonamidophenol ligands as extractants for trivalent actinides from alkaline high-level waste. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.Web of Science: 000478861201234
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2018Binding and extraction of trivalent lanthanides by tripodal sulfonamides and pyrazoles: structural, theoretical and spectroscopic studies. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.Web of Science: 000447609101517
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2018Complexation of Hg(II) and Cd(II) with rhodizonate and nitrogen donor ligands. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.Web of Science: 000435539907649
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2018Complexation, extraction, and sensing of Hg(II) by thioamide ligands and analogs. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.Web of Science: 000435537704298
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2018Spectroscopic study of lanthanide complexation by tripodal tris-(pyrazolyl) ligands. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.Web of Science: 000435537704308
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2017Coordination chemistry of the rhodizonate anion with Pb(II) and lanthanides: From understanding complexation to analytical applications. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.Web of Science: 000430569103467
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2017Soft N-, S-, and mixed donor site ligands for selective separation of actinides from lanthanides. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.Web of Science: 000430569105106
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2017Tripodal pyrazole ligands and analogs for selective ammonium and actinide extraction and sensing. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.Web of Science: 000430569104114
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2017Trivalent f-metal coordination and extraction by tripodal sulfonamide ligands and analogs. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.Web of Science: 000430569103635
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2017Investigation of Ln(III), An(III), and UO2+binding properties of soft N- and S-donor site ligands. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.Web of Science: 000429556701532
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2017Structural, spectroscopic, and theoretical studies on the effects of pyrazole substitution and ion-pairing in binding and sensing of NH4+and Lanthanides(III) by tripodal tris-pyrazole receptors. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.Web of Science: 000429556700084
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2014Cd(II) optical sensing by a thioamide ligand via ion-exchange extraction. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.Web of Science: 000348455202656
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2014Establishing a new REU site at a large department: Challenges, rewards, and lessons learned. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.Web of Science: 000348457605240
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2014Ratiometric detection of nitric oxide by fluorescent organometallic Re-phenanthroline complexes. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.Web of Science: 000348457602043
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2014Towards a dual-host approach for sensing of ammonium nitrate and other explosive salts: Intermolecular interactions between the dansyl fluorophore and anions lead to fluorescence enhancements. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.Web of Science: 000348455200231
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2014Towards selective Pb(II) complexation and fluorescence sensing by a phenazine disulfonamide ligand. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.Web of Science: 000348455202707
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2013Pb(II) vs. Cd(II) coordination chemistry, extraction, and sensing by thioamide and sulfonamide derivatives. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.Web of Science: 000324303601182
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2013Re-phenanthroline complexes as ratiometric fluorescent dyes for NO sensing. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.Web of Science: 000324303601309
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2013Transforming the "Survey of Chemistry" class for nursing students using the Learning Assistant (LA) model: Challenges and rewards. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.Web of Science: 000323851301869
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2012Manipulating metal coordination, ligand structure, and extraction energetics in an effort to design selective sensors for Pb(II) and other toxic metals. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.Web of Science: 000324503201457
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2012Metal complexes of phenanthroline and analogs as versatile frameworks for Nitric Oxide sensing and imaging. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.Web of Science: 000324503201124
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2012Pb(II) extraction and optical sensing by dinitro-phenylenediamine derivatives and phenazine analogs. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.Web of Science: 000324475102514
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2012Time-resolved study of caged Cu2+ photodissociation from nitrophenyl ligands and analogs. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.Web of Science: 000324475102511
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2008CHED 1167-Ferrocene derivatives of 1,2-phenylenediamine as electrochemical sensors and extractants for toxic metal ions. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.Web of Science: 000271775102777
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2008INOR 1076-Cd(II) coordination and selective extraction by disulfonamide ion exchangers. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.Web of Science: 000271775106365
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2007Coordination and extraction of Pb(II) and Cd(II) by disulfonamide chelates derived from 3,4-dimethoxyphenylsulfonylchloride and o-phenylenediamine. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 529-529.Web of Science: 000207722804527
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2007INOR 776-A tripodal ferrocenesulfonamide anion sensor derived from 1,3,5-tris(aminomethyl)-2,4,6-triethylbenzene. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 284-284.Web of Science: 000207722806284
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2007INOR 830-Electrochemical sensing of Pb(II) by small ferrocenylated peptide analogs containing cysteine (C) and glutamic acid (E). ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 281-281.Web of Science: 000207722806281
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2007INOR 900-Small peptides containing cysteine (C) and glutamic acid (E) residues as Pb(II) fluorescent sensors. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 276-276.Web of Science: 000207722806276
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2006An electroactive and fluorescent anion sensor: Anion binding properties of a tripodal anthraquinone sulfonamide derived from 1,3,5-tris(aminomethyl)-2,4,6-triethylbenzene. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.Web of Science: 000238125905489
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2006Coordination chemistry and solvent extraction as tools for designing sensors for Pb( II) and other toxic metals. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.Web of Science: 000238125904894
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2006Probing the formation of Pb(II)-disulfonamide complexes by ESI-MS. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.Web of Science: 000238125904651
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2005Sulfonamide ion exchangers for selective Pb extraction and sensing.. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. U1023-U1024.Web of Science: 000228177707407
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2005Synthesis and anion binding properties of a fluorescent tripodal N-dansylamide derived from 1,3,5-tris(aminomethyl)-2,4,6-triethylbenzene.. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. U541-U541.Web of Science: 000235066602227
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Proceedings Paper
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2010Analytical challenges of human arsenic metabolites. ARSENIC IN GEOSPHERE AND HUMAN DISEASES. 498-499.Web of Science: 000392030500196
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chaired theses and dissertations
- Lozano-Lewis, Lissette I, Organometallic Rhenium Dyes for Nitric Oxide Detection and Imaging 2015
- Currie, Richild Alecia, Spectroscopic, electrochemical and mass spectrometric investigation of anion binding by tripodal molecular receptors 2005
Research
principal investigator on
- FIU Nuclear Fellowship Program: Expanding the New FIU Radiochemistry Ph.D. Track awarded by U.S. Nuclear Regulatory Commission 2018 - 2022
- Nuclear Energy University Programs - Fellowships and Scholarship awarded by U.S. Department of Energy 2015 - 2022
- FIU Nuclear Fellowship Program: Supporting the new FIU Radiochemistry Ph.D. track awarded by U.S. Nuclear Regulatory Commission 2016 - 2020
- FIU Nuclear Research Fellowships Growing the Opportunities awarded by U.S. Nuclear Regulatory Commission 2015 - 2019
- FIU Nuclear Fellowship Program awarded by U.S. Nuclear Regulatory Commission 2014 - 2019
- Development of an Alternative Solvent Extraction Technology for Combined Cesium, Strontium, and Actinide Separation for High-Level Waste awarded by U.S. Department of Energy 2016 - 2019
- REU Site: Sensing, Monitoring, and Detection: From Molecules to Applications awarded by National Science Foundation 2016 - 2019
- FIU Nuclear Scholarship (FNS) Program awarded by U.S. Nuclear Regulatory Commission 2013 - 2017
- Development of an Alternative Solvent Extraction Technology for Combined Cesium and Actinide Separation for High-Level Waste Treatment awarded by U.S. Department of Energy 2015 - 2016
- REU Site: Sensing, Monitoring, and Detection: From Molecules to Applications awarded by National Science Foundation 2012 - 2016
co-principal investigator on
- Center for Actinide Science and Technology awarded by U.S. Department of Energy 2016 - 2019
- FIU Nuclear Scholarships for Health Physics and Radiochemistry awarded by U.S. Nuclear Regulatory Commission 2016 - 2018
- ISM Solutions Task Order awarded by Independent Strategic Management Solutio 2013 - 2014
investigator on
- 2007-2008 MBRS Support of Continuous Research Excellence at FIU. awarded by National Institutes of Health 2007 - 2009
Teaching
teaching activities
- CHM4910-U11: Undergraduate Research in Chemistry Fall Term 2019
- CHM6936-U02: Chemistry Colloquium Spring Term 2019
- CHM7910-U11: Dissertation Research Spring Term 2019
- CHM7910-U12: Dissertation Research Fall Term 2019
- CHM7980-U11: PH.D. Dissertation Spring Term 2019
- CHM7980-U12: PH.D. Dissertation Fall Term 2019
- CHS4100-U01: Radiochemistry Fall Term 2019
Contact
full name
- Konstantinos Kavallieratos
visualizations
Recent publications and grants in Scholars@FIU
publication subject areas
- Biochemistry & Molecular Biology
- Cell Biology
- Chemistry
- Crystallography
- Endocrinology & Metabolism
- Physics
- Spectroscopy