Intermolecular Re-H···H-N and Re-H···base hydrogen bonding estimated in solution by a UV-VIS spectroscopic method Article

Desmurs, P, Kavallieratos, K, Yao, W et al. (1999). Intermolecular Re-H···H-N and Re-H···base hydrogen bonding estimated in solution by a UV-VIS spectroscopic method . 23(11), 1111-1115. 10.1039/a906854f

cited authors

  • Desmurs, P; Kavallieratos, K; Yao, W; Crabtree, RH

abstract

  • Hydrogen bonding (Re-H···H-N) is estimated in solution between ReH05(PPh03)2L (L = pyridine, 4-picoline, 4-dimethylaminopyridine, and 4- carbomethoxypyridine), as hydrogen bond acceptor, and indole, as hydrogen bond donor. Re-H···base hydrogen bonding between- [Re(PPh3)2(MeCN)4H][BF4]2 as hydrogen bond donor and various amines as hydrogen bond acceptors is much weaker. The binding strengths are estimated by UV-VIS spectroscopy.

publication date

  • January 1, 1999

Digital Object Identifier (DOI)

start page

  • 1111

end page

  • 1115

volume

  • 23

issue

  • 11